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Hydrogen, a colourless, odourless and tasteless gas, consists of a single hydrogen atom. It is the lightest and most abundant element in the universe, and is found in only small quantities in the Earth’s atmosphere because it quickly escapes into space.
In industrial environments, hydrogen poses a major risk due to its high flammability. When combined with oxygen, it forms explosive mixtures that can detonate when exposed to sparks or heat. In addition, large quantities of hydrogen can displace oxygen, leading to a risk of suffocation.
Hydrogen is considered a promising energy source because it produces only water when burned and does not release any greenhouse gases. Its importance extends to ammonia production, energy generation in fuel cells, petroleum refining and many chemical processes.
Important information about hydrogen
Lower explosion limit (LEL) 4 vol. – %
| Konzentration | Symptome/folgen |
|---|---|
| 0.01 - 0.2 ppm | Normal concentration outdoors, no hazard. |
| 50 - 100 ppm | Initial symptoms of prolonged exposure, such as headaches and dizziness. |
| 200 - 400 ppm | After 2-3 hours, severe symptoms, including severe headache, dizziness, nausea and confusion. |
| 800 ppm and above | Fatal after 1-2 hours of exposure; at concentrations above 1600 ppm, it can be fatal within 20 minutes. |
Exposure to hydrogen (H2) can be life-threatening and requires immediate first aid. These first aid steps for hydrogen exposure should be followed:
Get fresh air immediately: Take the affected person outside immediately. Hydrogen has the ability to replace oxygen, which can lead to suffocation. Be careful and do not put yourself in danger.
Call the emergency services (112) and report your suspicion of hydrogen exposure or a possible incident. Provide as many details as possible, for example, whether the incident occurred at an industrial plant.
Ensure that the person is conscious and breathing normally. If the person is not breathing, start resuscitation (cardiopulmonary resuscitation) if you are trained to do so.
If possible, give the affected person oxygen via a face mask to improve their oxygen supply.
If the person is conscious but dazed, place them in the recovery position to prevent them from choking on their vomit or their airways becoming blocked.
Keep an eye on their breathing and consciousness until the emergency services arrive.
Communicate with the arriving emergency services and provide them with important information, such as the duration of exposure and the situation on site.
Never go back without adequate breathing protection or safety precautions if you suspect you may be returning to an area with hydrogen. Without prompt treatment, hydrogen exposure can have serious consequences; therefore, swift action is crucial.
In the event of an accidental release of hydrogen (H2), swift and coordinated action is crucial to minimise the risk to people in the vicinity. The following steps are recommended:
Leave the affected area immediately, especially if hydrogen equipment or systems are in operation nearby. Alert others in the vicinity and ensure that everyone leaves the area quickly and safely.
To remove hydrogen from the affected area and replace it with fresh air, open doors and windows as wide as possible. If available, activate ventilation systems to speed up ventilation.
If it is safe to do so, deactivate the hydrogen source (e.g. containers, pipes). Be careful and do not take any risks, as hydrogen is highly flammable.
Contact the emergency services (112) immediately to obtain professional assistance, especially if people are affected or the danger cannot be quickly eliminated. Provide clear information about the situation and the type of hydrogen source.
Only attempt to move people out of the danger zone if it is safe to do so and you are not putting yourself at risk. Keep in mind that hydrogen in high concentrations can displace oxygen.
If people show symptoms of hydrogen exposure (e.g. in the event of shortness of breath, dizziness or confusion), observe the first aid measures for oxygen deficiency:
– Take the person outside.
– Administer oxygen, if available.
– Monitor breathing and level of consciousness.
7. Warning and cordoning off: Cordon off the danger area to prevent others from accidentally entering it until the danger has been removed.
You should not enter the area without suitable respiratory protection, especially if the hydrogen concentration is high or you do not know what it is. Releasing hydrogen can cause serious accidents, so it is crucial to always act with caution and foresight.
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